|
Course
Code :: CH1201 |
(L-T-P) :: 2+4+0 |
Credits
:: 4 |
Detailed
Syllabus:
Scope and
limitations of thermo dynamics, definition and fundamental
concepts,
pressure, work, energy, heat. Equilibrium
state and phase rule.
Zeroth law
of thermodynamics First
law of
Thermodynamics: General statement, thermodynamic state
and state functions,
Internal energy, Enthalpy.The
steady-state steady-flow
process, Mass and energy
balances, equilibrium, the phase rule, the reversible process,
constant-V and
constant- P processes, heat capacity, isobaric, isochoric,
isothermal,
adiabatic and polytrophic processes.
Volumetric properties of pure substances :
The
PVT behavior of pure substances, virial equations, the ideal
gas, the
applications of the virial equations. Cubic equations of state,
generalized
correlations for gases, generalized correlations for liquids.
Heat
effects :
Sensible
heat effects, Internal energy of ideal gases: Microscopic view,
Latent heats of
pure substances, heat effects of industrial reactions, heat
effects of mixing
processes. Standard heat of reaction, Standard heat of
formation, Standard heat
of combustion, temperature dependence of heat of reaction
Second law of Thermodynamics-Statement, Heat engines,
thermodynamic temperatures scales,
thermodynamic temperature and the ideal gas scale.
Entropy,
Entropy changes of an ideal gas, mathematical statement of the
second law, the
third law of thermodynamics, entropy from the microscopic view
point,
calculation of ideal work and lost work.
Third law
of Thermodynamics.
Power
Cycles-Carnot cycle,
Rankine cycle, Otto cycle, Diesel cycle ,
Refrigeration
and liquefaction:
The
Carnot refrigerator, the vapor compression cycle, the comparison
of
refrigeration cycles, the choice of refrigerant, absorption
refrigeration, the
heat pump, liquefaction processes.
Text Books:
1.
"Introduction
to Chemical Engineering Thermodynamics" by J M Smith, H C Van
Ness and M M Abbott, 6th Edition, TMH.